Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 3, Pages 1018-1020Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03787g
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Funding
- Ministry of Education, Science and Technology [2010-0018456]
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Charge-compensated zinc metallocenes of types [(eta(3)-C2B9H10)(2)Zn]-[(eta(1)-NMe2)ZnEt](2) (5) and [{eta(3)-(Me)C2B9H9}(2)Zn][(eta(1)-NMe2)-ZnEt](2) (6) were produced by reacting sigma-/pi-chelating aminoalkyl dicarbollides, 7-Me2N(H)CH2-7,8-C2B9H11 (1) and 7-Me2N(H)CH2-8-Me-7,8-C2B9H10 (2), with diethylzinc. Zincocene 5 proved to be an excellent synthon for the formation of dicarbollide-based sigma-/pi-type constrained Ru and Ni complexes.
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