Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 3, Pages 878-880Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03295f
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- CNRS
- ANR
- UBO
- ministere de l'Enseignement Superieur, de la Recherche Scientifique et de la Technologie of Tunisia
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A new dissymmetrically disubstituted diiron dithiolate species, [Fe-2(CO)(4)(kappa(2)-(P2N2Ph)-N-Ph)(mu-pdt)] (pdt = S(CH2)(3S)), was prepared by using a flexible cyclic base-containing diphosphine, 1,3,5,7-tetraphenyl 1,5-diaza-3,7-diphosphacyclooctane ((P2N2Ph)-N-Ph = {PhPCH2NPh}(2)). Preliminary investigations of proton and electron transfers on the diiron system have been done.
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