Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 7, Pages 2023-2025Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04049e
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Funding
- NSF of China [20703032, 11074210, 20620130427, 20533040]
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We present the first in situ surface Raman spectra of hydrogen on rhodium under electrochemical conditions using gold-core rhodium-shell (Au@Rh) nanoparticles for SERS or gold-core silica-shell (Au@SiO2) nanoparticles for SHINERS. The advantage of SHINERS lies in the versatility to study single crystal surfaces such as the H-Rh(111) system.
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