4.7 Article

Bow-tie metallo-cryptophanes from a carboxylate derived cavitand

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 1, Pages 176-178

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01284j

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Funding

  1. EPSRC
  2. STFC
  3. EPSRC Mass Spectrometry Service in Swansea
  4. EPSRC [EP/E023517/1] Funding Source: UKRI
  5. Engineering and Physical Sciences Research Council [EP/E023517/1] Funding Source: researchfish

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A new carboxylic acid functionalised cavitand forms [Cu(3)L(2)] metallo-cryptophanes with Cu(OAc)(2) that can be linked together into dimers with the bridging ligand 1,2-bis(4-pyridyl)ethylene. Reaction of the cavitand with Co(OAc)(2) gives a metallo-cryptophane with a central Co(7) cluster.

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