Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 27, Pages 7845-7847Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12263k
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Funding
- National Natural Science Foundation of China [21032003, 20872140]
- National Basic Research Program of China [2010CB833300]
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Highly enantioselective hydrogenation of seven-membered cyclic imines, substituted dibenzo[b,f][1,4]oxazepines, was achieved, with up to 94% ee, by using the [Ir(COD)Cl](2)/(S)-Xyl-C-3(*)-TunePhos complex as the catalyst in the presence of morpholine-HCl.
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