4.7 Article

Simultaneous enhancement of chemical shift dispersion and diffusion resolution in mixture analysis by diffusion-ordered NMR spectroscopy

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 25, Pages 7063-7064

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12456k

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Funding

  1. Engineering and Physical Sciences Research Council [EP/H024336/1, EP/I007989/1, EP/E05899X/1]
  2. EPSRC [EP/H024336/1, EP/I007989/1, EP/E05899X/1] Funding Source: UKRI

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Mixture analysis by high resolution diffusion-ordered NMR spectroscopy (HR-DOSY) requires differences in both chemical shift and diffusion coefficient; resolution can be greatly enhanced by exploiting the chemical specificity of lanthanide shift reagent binding to increase chemical shift and diffusion dispersion simultaneously.

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