Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 18, Pages 5181-5183Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04835f
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- NSERC (Canada)
- ORDCF (Ontario)
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Pd-PEPPSI-IPent has proven to be an excellent catalyst for the Negishi cross-coupling reaction of secondary alkylzinc reagents with a wide variety of aryl/heteroaryl halides. Importantly, beta-hydride elimination/migratory insertion of the organometallic leading to the production of isomeric coupling products has been significantly reduced using the highly-hindered Ipent ligand.
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