Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 11, Pages 3025-3042Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04506c
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- CNCSIS [IDEI 1912/2009]
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The binuclear complexes (3d-3d, 3d-3d', 3d-4f) with compartmental ligands can efficiently act as tectons in crystal engineering. Various high nuclearity clusters and coordination polymers can be easily obtained by choosing the appropriate spacers. The main interest in such systems arises from their magnetic and photophysical properties. Moreover, 3d-3d' and 3d-4f complexes are useful precursors in designing heterotrimetallic systems with relevance in molecular magnetism.
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