Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 3, Pages 1030-1032Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03391j
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [18GS0207]
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A S/SH bridged hetero-dinuclear Ru/Ge complex cation reacted with H-2 to afford the mu-S/mu-H complex. The reaction was considerably slower compared to that of the mu-S/mu-OH complex. Thus, the mu-S/mu-SH and mu-S/mu-OH complexes might provide models for the unready and ready states, respectively, of [NiFe] hydrogenase.
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