4.7 Article

KCN sensor: unique chromogenic and 'turn-on' fluorescent chemodosimeter: rapid response and high selectivity

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 10, Pages 2886-2888

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05018k

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Funding

  1. CRI [2010-0000728]
  2. NRF [20100001630]
  3. Sungkyunkwan University

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An indole conjugated coumarin 1 for KCN chemodosimeter has been prepared and displayed considerable dual changes in both absorption (blue-shift) and emission (turn-on) bands exclusively for KCN. DFT/TDDFT calculations support that the fluorescence enhancement of 1-KCN is mainly due to blocking of the ICT process.

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