4.7 Article

A fast and selective decarboxylative difunctionalization and cyclization for easy access to gem-dihalo alcohol, ether, ester and bromo-1,4-dioxane

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 47, Pages 12667-12669

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc16126a

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Funding

  1. DST [SR/NM/NS-29/2010, SR/S1/OC-22/ 2006]
  2. CRNN
  3. CSIR, India

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A general strategy for fast decarboxylative difunctionalization to gem-dihalohydrin, gem-dihaloether, gem-dibromoester and cyclized bromo-1,4-dioxane synthons with outstanding regio- and stereoselectivity is demonstrated.

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