Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 43, Pages 11852-11854Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14836b
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Funding
- Department of Energy-Basic Energy Sciences [DE-SC0002235]
- NSF [DMR-0846958]
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Reported here is a rare example of a highly symmetrical chiral Mg-based MOF (CPF-1) with nanotubular channels, built from 4(1) (or 4(3)) helical chains. It exhibits a high gas sorption capacity (ca. 1.29 wt% H-2 at 77 K, 1 atm; 84 cm(3) g(-1) of CO2 at 273 K, 1 atm).
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