4.7 Article

A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis-alkyl transfer mechanism

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 10, Pages 2979-2981

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04986g

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Funding

  1. CNRS
  2. French Government through the ANR [ANR 07-CP2D-21-02]
  3. Competitiveness Cluster on Chemistry and Environment of Lyon1 Rhone-Alpes (Axelera)
  4. [TGE RMN THC Fr3050]

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Impregnation of [(AliBu(3))(Et2O)] on partially dehydroxylated SBA-15 affords a mesoporous material bearing the well-defined single site surface aluminium species [( SiO)(2)Al(iBu)(Et2O)].

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