Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 27, Pages 7833-7835Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10912j
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Funding
- RFBR [09-03-93105]
- Haldor Topsoe company
- [02.740.11.0628]
- [14.740.11.0273]
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The first Keggin-type heteropolyanion, [PW11O39Ir(H2O)](4-) (1), was synthesized by hydrothermal reaction from two different polytungstate precursors and [IrF6](2-). It was isolated as (Bu4N)(4)[PW11O39Ir(H2O)] (1a), which was completely characterized by multinuclear P-31 and W-183 NMR, ESI-mass spectrometry and cyclic voltammetry. A rapid screening methodology to ascertain the intrinsic substitutional lability at the Ir site is also presented, based on ESI-MS.
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