Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 27, Pages 7857-7859Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12969d
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) [22550103]
- Grants-in-Aid for Scientific Research [22550103] Funding Source: KAKEN
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A low-valent titanium species derived in situ from Ti(O-i-Pr)(4), Me3SiCl and Mg powder in tetrahydrofuran reacted with epoxides to selectively provide less hindered alcohols via a homolytic ring-opening of epoxides, in which the intermediate beta-titanoxy radical intramolecularly abstracted a hydrogen atom from an alkoxy moiety in the titanium complexes.
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