4.7 Article

Debundling, selection and release of SWNTs using fluorene-based photocleavable polymers

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 26, Pages 7428-7430

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11400j

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Funding

  1. DFG Center for Functional Nanostructures (CFN)
  2. Helmholtz Programme POF NanoMikro
  3. Karlruhe Institute of Technology (KIT)
  4. University of Basel

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Photocleavable polymers based on 9,9-dialkylfluorene backbone and o-nitrobenzylether were designed and synthesized to obtain stable (n, m) enriched suspensions of semiconducting SWNTs in toluene. Photoirradiation of the suspensions triggered the precipitation of the SWNTs and TEM images indicate close packing of SWNTs pointing at partial removal of the coating polymer.

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