Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 24, Pages 6927-6929Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11864a
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- Ministry of Education, Culture, Sports, Science and Technology, Japan [WAKATE B-1975011]
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Introduction of bulky substituents such as benzyl and pyrenyl groups using click reactions inhibited or slowed the rotation of the units on the NMR chemical shift timescale. The perpyrenylated pillar[5]arene showed a thermally-responsive excimer emission, but a unit model of the perpyrenylated pillar[5]arene did not exhibit such a response.
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