Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 6, Pages 1836-1838Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02612c
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Funding
- NSFC [20621091, 20672048, 20732002, 20972059]
- MOE
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The first total synthesis of polycyclic Stemona alkaloid maistemonine has been achieved. The efficient approach features a stereoselective intramolecular Schmidt reaction, a ketone-ester condensation, and a Reformatsky reaction. Additionally, another Stemona alkaloid stemonamide was divergently synthesized from a common intermediate.
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