Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 4, Pages 1342-1344Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02347g
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Funding
- Natural Sciences Foundation of China [20821002, 20932008]
- Major State Basic Research Development Program [2009CB825300]
- Chinese Academy of Sciences
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A pyridine-catalyzed ylide cyclization affording dihydrofurans and dihydropyrroles has been developed. In the presence of a catalytic amount of pyridine and Fe(Tcpp)Cl, alpha-ylidene-beta-diketones and alpha, beta-unsaturated imines react with diazoacetates providing dihydrofurans and dihydropyrroles respectively, in up to 96% yield with high diastereoselectivities.
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