4.7 Article

A novel hole transport material for iodine-free solid state dye-sensitized solar cells

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 37, Pages 10395-10397

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13376d

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Funding

  1. Energy RD program [20093020010040]
  2. MKE
  3. Basic Science Research Program [2009-0093462]
  4. NRF [2010-0019119]
  5. MEST (Korea)
  6. BK21 (Brain Korea 21)
  7. POSCO

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A novel bis-EDOT-based monomer with ethylene glycol oligomers was synthesized and shown to exhibit strong ion solvation, good transport properties, and effective charge screening. These properties greatly improved J(SC) (4.2 to 7.0 mA cm(-2)) and eta (1.6 to 2.9%) in an iodine-free solid state dye-sensitized solar cell (DSSC) employing a Z-907 sensitizer, compared with the corresponding values of DSSCs fabricated using the standard bis-EDOT.

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