Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 36, Pages 10109-10111Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13787e
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Funding
- National Science Foundation [CHE-0808909]
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The half-sandwich tamoxifen derivative, Mn(CO)(3)(eta(5)-C5H4(Et)C=C(C6H5)(2)), gives a radical cation which is charge-delocalized between the cymantrenyl and diphenylethene moieties and undergoes facile metal-carbonyl substitution reactions. Mn and Re complexes with finely tuned redox potentials can be obtained for cancer cell inhibition studies.
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