4.7 Article

Temperature-dependent conductivity of Emim(+) (Emim(+)=1-ethyl-3-methyl imidazolium) confined in channels of a metal-organic framework

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 43, Pages 11933-11935

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14702a

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Funding

  1. NNSFC [20825103, 90922031, 21021061]
  2. MSTC [2007CB815304, 2012CB821704]

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A 3D metal-organic framework, featuring three kinds of cation channels, was obtained through an ionothermal reaction. Investigation on its temperature-dependent conductivity indicates the contribution of order and disorder of the Emim(+) (Emim(+) = 1-ethyl-3-methyl imidazolium bromide) in the channel to its conductivity.

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