4.7 Article

Phosphirenium-borate zwitterion: formation in the 1,1-carboboration reaction of phosphinylalkynes

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 37, Pages 10482-10484

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13008k

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Funding

  1. Deutsche Forschungsgemeinschaft

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Reaction of the acetylene Mes(2)P-C C-Ar with B(C6F5)(3) at rt gives a zwitterionic phosphirenium product, which reacts further at >100 degrees C to complete the 1,1-carboboration reaction.

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