4.7 Article

Transfer hydrogenation of unfunctionalised alkenes using N-heterocyclic carbene ruthenium catalyst precursors

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 31, Pages 8802-8804

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12923f

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Funding

  1. European Research Council [ERC-StG 208561]
  2. COST Action [D40]

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Transfer hydrogenation of unfunctionalised and aliphatic alkenes in iPrOH/KOH is efficiently catalysed by an olefin-tethered N-heterocyclic carbene ruthenium complex, which also catalyses double bond migration as a competitive and considerably faster process.

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