4.7 Article

Frontal polymerizations carried out in deep-eutectic mixtures providing both the monomers and the polymerization medium

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 18, Pages 5328-5330

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10391a

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Funding

  1. CONACyT [78798]
  2. Autonomous University of Queretaro (UAQ)
  3. CONCyTEQ
  4. MICINN [MAT2009-10214, PET2008-0168-01]

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Deep Eutectic Solvents (DESs) based upon mixtures of Acrylic Acid (AA) or Methacrylic Acid (MAA) and Choline Chloride (CCl) demonstrated superior performance than regular organic solvents and even ionic liquids for frontal polymerizations (FPs). Full recovering of CCl after FP provided an interesting green character to the process.

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