Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 26, Pages 7491-7493Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11870f
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Funding
- GlaxoSmithKline
- EPSRC [RAS: EP/E055346, CR: EP/F068352]
- Engineering and Physical Sciences Research Council [EP/F068352/1] Funding Source: researchfish
- EPSRC [EP/F068352/1] Funding Source: UKRI
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The synthetic utility of S-mesitylsulfinimines for the synthesis of chiral amines and aziridines was examined through their reactions with Grignard reagents, with the ylides derived from trimethylsulfonium iodide and S-allyl-tetrahydrothiophenium bromide and through an aza-Darzens manifold, affording convenient access to a diverse range of highly substituted chiral amines and aziridines in high yields and excellent stereoselectivities.
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