Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 31, Pages 8919-8921Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12460a
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Funding
- EPSRC [EP/H000925/1, EP/G061785/1]
- Dutch Polymer Institute
- Royal Society
- Engineering and Physical Sciences Research Council [EP/H000925/1] Funding Source: researchfish
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A [2 + 3] organic cage compound based on the condensation reaction of 1,3,5-tri(4-formylphenyl)benzene with 1,5-pentanediamine was synthesized. The resulting porous molecular crystal demonstrates selective adsorption of hydrogen and carbon dioxide over nitrogen. As for porous polymer membranes, a trade-off between sorption capacity and selectivity is observed for materials in this class.
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