Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 12, Pages 3389-3391Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05559j
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Funding
- EPSRC [EP/H000925/1]
- Engineering and Physical Sciences Research Council [EP/H000925/1] Funding Source: researchfish
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The coordination of adenine to Ni2+ forms a dimer unit which can be linked by 3,5-pyrazoledicarboxylic acid into chains which assemble under hydrothermal conditions via hydrogen bonding into a robust porous network. The material displays selectivity for CO2 over CH4 and an isosteric heat which increases with guest loading.
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