Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 2, Pages 713-715Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03882b
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- Advantage West Midlands (AWM)
- European Regional Development Fund (ERDF)
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The flexible metal-organic framework MIL-53(Cr) undergoes a dramatic volume expansion upon immersion in water at room temperature to form a crystalline hydrate in which water is held as a hydrogen-bonded tube: the hydration is readily reversible under ambient conditions as shown by time-resolved powder X-ray diffraction.
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