4.7 Article

Matrix-dependent cooperativity in spin crossover Fe(pyrazine)Pt(CN)(4) nanoparticles

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 41, Pages 11501-11503

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14463d

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Funding

  1. Higher Education Commission of Pakistan
  2. French Ministry of Research (ANR) [ANR-08-JCJC-0085-01]
  3. METSA network

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Anisotropic nanoparticles of the Fe(pyrazine)Pt(CN)(4) network were prepared embedded in various matrices that revealed to have a dramatic effect on the cooperative spin crossover phenomena. By a judicious choice of the nature of the matrix and the control of interparticle distances, a hysteresis of 15 K was achieved close to room temperature for such nano-objects.

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