4.7 Article

Single molecule magnet behaviour in robust dysprosium-biradical complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 35, Pages 6458-6460

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00966k

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Funding

  1. Italian MURST
  2. EC [MRTN-CT-2003-504880, NMP3-CT-2005-515767, FP7-ICT-2007-C-211284]
  3. German DFG [SPP1137]

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A Dy-biradical complex was synthesized and characterized down to very low temperature. ac magnetic measurements reveal single molecule magnet behaviour visible without any application of dc field. The transition to the quantum tunneling regime is evidenced. Photophysical and EPR measurements provide evidence of the excellent stability of these complexes in solution.

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