Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 3, Pages 398-400Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b921559j
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Funding
- NSF Center for Chemical Innovation [CHE-0802907, CHE-9808061, DBI-9729592]
- Chesonis Family Foundation
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Aryl-substituted tetraimine complexes related to Co(dmgBF(2))(2)(MeCN)(2) (dmg = dimethylglyoxime) were synthesized and are active for hydrogen evolution. Co(dmgBF2) 2(MeCN) 2 can be adsorbed to a glassy carbon electrode. The chemically modified electrode is active for hydrogen evolution in aqueous solution at pH < 4.5, with an overpotential of only 100 mV.
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