4.7 Article

Nanosized anatase TiO2 single crystals for enhanced photocatalytic activity

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 5, Pages 755-757

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b919895d

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Funding

  1. Major Basic Research Program, Ministry of Science and Technology of China [2009CB220001]
  2. NSFC [50921004]
  3. Solar Energy Program of Chinese Academy of Sciences
  4. IMR SYNL-T.S. Ke Research Fellowship
  5. Australian Research Council [DP0666345]

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Nanosized anatase TiO2 single crystals with 18% {001} facets have a raised conduction band minimum by 0.1 eV, and exhibit photocatalytic activity both for generating (OH)-O-center dot radicals and for splitting water into hydrogen that is markedly superior-by factors of 5.6 and 8.2, respectively-to reference ca. 3 mu m anatase TiO2 with 72% {001} facets.

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