4.7 Article

A rod packing microporous metal-organic framework with open metal sites for selective guest sorption and sensing of nitrobenzene

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 38, Pages 7205-7207

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01236j

Keywords

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Funding

  1. NSF [CHE 0718281]
  2. Welch Foundation [AX-1730]
  3. National Natural Science Foundation of China [50625206, 50928201, 50972127]

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A microporous MOF [Zn(4)(OH)(2)(1,2,4-BTC)(2)] (1,2,4-BTC = Benzene-1,2,4-tricarboxylate) with two immobilized open metal Zn(2+) sites was obtained by solvothermal reaction, which exhibits highly selective guest sorption and sensing of nitrobenzene.

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