Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 18, Pages 3203-3205Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b925415c
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A N-heterocyclic carbene, namely, 1,3-bis-(diisopropyl)imidazol-2-ylidene either directly initiates or catalyzes the metal-free ring opening polymerization of neat propylene oxide at 50 degrees C, affording well-defined alpha,omega-heterodifunctionalized poly(propylene oxide) oligomers.
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