Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 35, Pages 6569-6571Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01084g
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The Mn(hfac)(2) complex of the paramagnetic 4-(benzoxazol-2'-yl)-1,2,3,5- dithiadiazolyl ligand is reported (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato-). The Mn(II) and radical ligand spins are coupled antiferromagnetically (AF) in the coordination complex. Short sulfur-oxygen contacts between molecules provide an efficient pathway for AF coupling between the radical ligand of one molecule and the Mn(II) of a neighbouring molecule, resulting in a large total spin ground state (S(T) = 4) for a pair of molecules.
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