4.7 Article

New azaborine-thiophene heteroacenes

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 37, Pages 7007-7009

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01963a

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Funding

  1. NSERC
  2. FQRNT

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A new class of heteroacenes containing B, N and S elements in the 22-electron aromatic nucleus has been synthesized by reaction of diaminoterthiophenes with dichlorophenylborane. Their structure was studied by X-ray crystallography and DFT calculations. UV-Vis absorption /emission spectroscopy shows high rigidity and deep-blue fluorescence of these compounds.

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