Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 16, Pages 2713-2723Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c001392g
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Funding
- ICIQ
- ICREA
- Spanish Ministry of Science and Innovation (MICINN) [CTQ2008-02050/BQU]
- Spanish Ministry of Education (FPU)
- ICREA Funding Source: Custom
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Metallosalen complexes are able to catalyze several transformations via a bimetallic, cooperative pathway. Various strategies to induce simultaneous activation by two metal centers with multinuclear catalysts have been reported to date, leading to higher reaction rates and selectivities in existing reactions. In some cases, new reactions could be realized that were previously not possible. The design principles, the most successful approaches and the catalytic applications of multinuclear metallosalen catalysts are discussed in this feature article.
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