Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 32, Pages 5936-5938Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01091j
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Funding
- Generalitat de Catalunya (GC) [2009SGR1041, XRQTC]
- Spanish MICINN [FIS2008-02238, CTQ2007-30547-E/BQU]
- NSF Bulgaria [DTK02/36, DO02-115]
- ICREA Funding Source: Custom
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The formation of oxygen vacancies in nanoparticles CenO2n (n <= 80), studied using density-functional calculations, is found to be greatly facilitated compared to extended surfaces, which explains the observed spectacular reactivity of nanostructured ceria.
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