Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 48, Pages 9218-9219Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03801f
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- Ministero dell'Istruzione, dell'Universita e della Ricerca [2007X2RLL2]
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We report on three Ir(III) molecular catalysts for water oxidation: 1, [Cp*Ir(ppy) Cl]; 2, [Cp*Ir(bzpy)NO3]; 3, [Cp*Ir(H2O)(3)](NO3)(2). 2 and 3 are water-soluble and show a long-term activity ca. 2 and 3 times higher than 1. It is remarkable that 3, having the simplest structure, is the catalyst with the highest activity.
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