☆ 4.7 Article

Flexibility of cubane-like Cu4I4 framework: temperature dependence of molecular structure and luminescence thermochromism of [Cu4I4(PPh3)(4)] in two polymorphic crystalline states

CHEMICAL COMMUNICATIONS (2010)

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Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 34, Pages 6302-6304

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01434f

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Categories

Chemistry, Multidisciplinary

Funding

  1. Japan Society for the Promotion of Science (JSPS) [21550065]
  2. Sugiyama Houkoukai Fund

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Multitemperature X-ray structure analyses and photoemission spectra of [Cu4I4(PPh3)(4)] in two polymorphic crystals reveal that the cubane-like framework is flexibly distorted effecting luminescence thermochromism.

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