4.7 Article

Imma perovskite-type oxynitride LaTiO2N: structure and electron density

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 26, Pages 4704-4706

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00573h

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Funding

  1. Ministry of Education, Science, Sports and Culture

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We present the first example of Imma perovskite-type oxynitride. LaTiO2N was found to have an Imma perovskite-type structure with a(0)b(-)b(-) tilt system. The Ti-(O,N) covalent bonding and existence of N atoms are responsible for the reduced band gap of LaTiO2N photocatalyst.

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