Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 36, Pages 6786-6788Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02030c
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Funding
- CAS [09i4281c10]
- NSF of China [20835005]
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We found that melamine in its protonated form could be triggered by oxoanions such as NO(3)(-), PO(4)(3-), ATP, and SO(4)(2-) to form superstructures and to gelate a large amount of water molecules, presumably resulting from the electrostatic and hydrogen bonding interactions operating in a synergistic manner; the gelation can be reversibly switched off/on by increasing/decreasing pH or temperature.
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