4.7 Article

Deprotonative metallation of ferrocenes using mixed lithium-zinc and lithium-cadmium combinations

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 16, Pages 2862-2864

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b924939g

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Funding

  1. Rennes Metropole, Region Bretagne
  2. University of Rennes 1
  3. CNRS

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A mixed lithium-cadmium amide and a combination of lithium and zinc amides were reacted with a range of ferrocenes; deprotonative mono- or dimetallation in general occurred chemoselectively at room temperature, as evidenced by subsequent quenching with iodine.

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