4.7 Article

Highly activated Michael acceptor by an intramolecular hydrogen bond as a fluorescence turn-on probe for cyanide

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 48, Pages 9197-9199

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03910a

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Funding

  1. National Research Foundation of Korea [2010-0008165]
  2. Hankuk University of Foreign Studies

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An activated Michael acceptor type of probe by an intramolecular hydrogen bond has shown a selective fluorescence turn-on response to cyanide through a conjugated addition of the nucleophilic anion to the enone probe with a 1300-fold increase in its fluorescence intensity.

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