4.7 Article

Carborane-Bodipy scaffolds for through space energy transfer

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 42, Pages 7978-7980

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02656e

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Use of a closo-1,12-dicarbadecaborane backbone to link two different organic dyes separated by ca. 37 angstrom promotes exclusive through space electronic energy transfer with an efficiency of 81 to 87% with Stoke shifts between 4750 and 2800 cm(-1) depending on the pH.

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