Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 42, Pages 8011-8013Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02606a
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Nanoparticles of the [Fe(NH(2)trz)(3)](tosylate)(2) spin crossover complex of 3-4 nm size were synthesized and dispersed in a nonionic surfactant. This colloidal system exhibits thermal spin crossover phenomena associated with a virtually first order transition. By thermal treatment the colloidal suspension can be transformed into a fibrous structure forming a gel.
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