4.7 Article

Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 15, Pages 2614-2616

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b923028a

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Funding

  1. Jilin Province [20090158]
  2. NENU'S Scientific Innovation Project [NENU-STC07004]
  3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University

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A new chiral open-framework cobalt phosphite [C6N2H14][Co(HPO3)(2)] (1) with helical channels has been synthesized under solvothermal conditions in the presence of achiral organic amine. The circular dichroism (CD) spectrum indicates that the bulk crystals have optical activity. Magnetic measurements reveal that 1 is a weak ferromagnet.

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