4.7 Article

Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 41, Pages 7724-7726

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02041a

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Funding

  1. Michigan Economic Development Corp.
  2. NIH [GM63188, GM45617]
  3. NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM063188, R56GM063188, R01GM045617] Funding Source: NIH RePORTER

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Experiment and theory favour a model of C-H borylation where significant proton transfer character exists in the transition state.

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