Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 41, Pages 7796-7798Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03107k
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Funding
- Fudan University
- National Natural Science Foundation of China [20902011]
- Shanghai Municipal Science and Technology Commission [10QA1400500, 2010MCIMKF04]
- German Science Foundation (DFG) [SFB 624]
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A novel robust pyridine-bridged bis-benzimidazolylidene nickel pincer complex 3 accessible from inexpensive, commercially available precursors efficiently catalyzes the first practical Suzuki-Miyaura cross-coupling reactions with various less-reactive electrophiles ArX ( X = Br, Cl, OTs and OMs) and even tolerates electron-rich, sterically demanding and heterocyclic arenes in the presence of catalytic amounts of PPh3.
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